Product ID:FLEET CHARGE 60/40 ANTIFREEZE & COOLANT
MSDS Date:05/15/2000
FSC:6850
NIIN:01-464-9096
MSDS Number: CLCZV

OLD WORLD INDUSTRIES INC

4065 COMMERCIAL AVE
NORTHBROOK, IL 60062-1851
US

Emergency Phone: (800) 424-9300

Info Phone: 847-559-2173

Cage: 0U3B1

OLD WORLD INDUSTRIES INC

NORTHBROOK, IL 60062-1851 US

Telephone: 847-559-2173

Cage: 0U3B1

ETHYLENE GLYCOL

CAS: 107-21-1

RTECS: KW2975000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:LD50 (RATS) 6000-13000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SLIGHT TRANSIENT IRRITATION.
SKIN: REPEATED SKIN EXPOSURE MAY RESULT IN ABSORPTION OF HARMFUL
AMOUNTS. INGESTION: SINGLE DOES ORAL TOXICITY IS CONSIDERED TO BE
MODERATE. EXCESSIVE EXPOSURE MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS, CARDIOPULMONARY EFFECTS (METABOLIC ACIDOSIS), & KIDNEY
FAILURE. SWALLOWING LARGE AMOUNTS MAY CAUSE SERIOUS INJURY, EVEN
DEATH. INHALATION: HIGHER TEMPERATURES M AY GENERATE VAPOR LEVELS
SUFFICIENT TO CAUSE ADVERSE EFFECTS.
Explanation of Carcinogenicity:BASED ON DATA FROM LONG-TERM ANIMAL
STUDIES, ETHYLENE GLYCOL IS NOT BELIEVED TO POSE A CARCINOGENIC
RISK TO MAN.
Effects of Overexposure:EXCESSIVE EXPOSURE MAY CAUSE NAUSEA AND/OR
VOMITING. MAY ALSO CAUSE ANESTHETIC OR NARCOTIC EFFECTS.
TERATOLOGY: EXPOSURE TO ETHYLENE GLYCOL HAS CAUSED BIRTH DEFECTS N
LABORATORY ANIMALS ONLY AT DOS ES TOXIC TO THE MOTHER.
REPRODUCTIVE EFFECTS: ETHYLENE GLYCOL HAS NOT INTRFERED WITH
REPRODUCTIVE IN ANIMAL STUDIES EXCEPT AT VERY HIGH DOSES.

First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR 15
MIN, LIFTING EYE LIDS. GET MEDICAL ATT'N IMMEDIATELY. SKIN: FLUSH
AREA WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN WHILE REMOVING
CONTAM INATED CLOTHING. INHALATION: IMMEDIATELY REMOVE VICTIM TO
FRESH AIR & CALL EMERGENCY MEDICAL CARE. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: I F FULLY CONSCIOUS, GIVE TWO GLASSES OF WATER. DO NOT
INDUCE VOMITING. GET MEDICAL ATT'N AS NEEDED FOR ALL ROUTES OF
EXPOSURE.

Flash Point Method:SCC
Flash Point:=119.C, 246.2F
Lower Limits:3.2%
Upper Limits:22%
Extinguishing Media:WATER FOG OR FINE SPRAY. ALCOHOL RESISTANT FOAMS
(ATC TYPE) ARE PREFERRED IF AVAILABLE. GENERAL PURPOSE SYNTHETIC
FOAMS (INCLUDING AFFF) OR PROTEIN FOAMS MAY FUNCTION.
Fire Fighting Procedures:WEAR POSITIVE-PRESSURE, SELF-CONTAINED
BREATHING APPARATUS (SCBA) AND PROTECTIVE FIRE FIGHTING CLOTHING
(INCLUDES FIRE-FIGHTING HELMET, COAT, PANTS, BOOTS AND GLOVES).
Unusual Fire/Explosion Hazard:NO FIRE & EXPLOSION HAZARDS EXPECTED
UNDER NORMAL STORAGE & HANDLING CONDITIONS (I.E., AMBIENT
TEMPERATURES). HOWEVER, ETHYLENE GLYCOL OR SOLUTIONS OF ETHYLENE
GLYCOL & WATER CAN FORM FLAMMABLE VAPORS W/ AIR IF HEATED
SUFFICIENTLY. KEEP PEOPLE AWAY. ISOLATE FIRE AREA & DENY
UNNECESSARY ENTRY.

Spill Release Procedures:KEEP PEOPLE AWAY FROM SPILL SITE. PVC-COATED
GLOVES & MONOGOGGLES OR FACESHIELD CAN BE USED DURING CLEANUP OF
SPILL SITE. SMALL SPILLS: SOAK UP WITH ABSORBENT MATERIAL. LARGE
SPILLS: DIKE & PUMP INTO SUITABLE CONTAINERS FOR DISPOSAL. ENSURE
COMPLIANCE WITH ALL APPLICABLE STATUES THAT REQUIRE NOTIFICATION OF
APPROPRIATE GOVERNMENT OFFICIALS.

Handling and Storage Precautions:PRODUCT ON SURFACES CAN CAUSE SLIPPERY
CONDITIONS. PRACTICE REASONABLE CARE AND CLEANLINESS. AVOID
BREATHING SPRAY MISTS IF GENERATED. KEEP OUT OF REACH OF CHILDREN.
PRODUCT MAY BECOME A SOLID AT TEMP ERATURES BELOW -18C (0F). DO NOT
STORE NEAR FOOD, FOODSTUFFS, DRUGS OR POTABLE WATER SUPPLIES.

Respiratory Protection:RESPIRATORY PROTECTION IS REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT ANY DETECTABLE CONCENTRATION, ANY
SCBA W/ A FULL FACEPIECE & OPERATED IN A PRESSURE-DEMAND OR OTHER
POSITIVE PRESSURE MODE OR ANY SUPPLIED-AIR RESPIRATOR W/ A FULL
FACEPIECE & OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE
PRESSURE MODE IN COMBINATION W/ AN AUXILIARY SCBA OPERATED
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:POLYETHYLENE; NEOPRENE; NITRILE; PLYVINYL ALCOHOL;
NATURAL RUBBER, BUTYL RUBBER
Eye Protection:SAFETY GOGGLES AND FACE SHIELD.
Other Protective Equipment:PROTECTIVE GLOVES RECOMMENDED WHEN PROLONGED
SKIN CONTACT CANNOT BE AVOIDED. SAFETY SHOWER SHOULD BE AVAILABLE.
EMERGENCY EYEWASH SHOULD BE AVAILABLE.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING
WITH THIS CHEMICAL.
Supplemental Safety and Health
ESCAPE: ANY AIR-PURIFYING FULL FACEPIECE RESPIRATOR (GAS MASK) WITH A
CHIN-STYLE OR FRONT-OR-BACK-MOUNTED ORGANIC VAPOR CANISTER OR ANY
APPROPRIATE ESCAPE-TYPE SELF-CONTAINED BREATHING APPARATUS.

HCC:V5
Boiling Pt:=132.2C, 270.F
Melt/Freeze Pt:=-48.3C, -55.F
M.P/F.P Text:-55F TO -65F
Vapor Pres:<0.1
Vapor Density:2.1
Spec Gravity:1.085 - 1.095
pH:10 - 11
Evaporation Rate & Reference:NIL
Solubility in Water:COMPLETE
Appearance and Odor:GREEN; MILD ODOR
Percent Volatiles by Volume:97.0

Stability Indicator/Materials to Avoid:YES
ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES, CHROMATES &
PEROXIDES.
Stability Condition to Avoid:ISOLATE FROM OXIDIZERS, HEAT & OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE FROM
BURNING.
Conditions to Avoid Polymerization:MATERIAL IS NOT KNOWN TO POLYMERIZE

Waste Disposal Methods:DO NOT DISCHARGE TO SEWER. WEAR APPROPRIATE
PERSONAL PROTECTION. TAKE UP WITH SAND, VERMICULITE, OR SIMILAR
INERT MATERIAL. DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.

Toxicological Information:INGESTION: THE LETHAL DOSE IN HUMANS IS
ESTIMATED TO BE 100 ML (3 OUNCES). THE ORAL LD50 FOR RATS IS IN THE
5000-13,000 MG/KG RANGE. MUTAGENICITY: IN VITRO MUTAGENICITY
STUDIES WERE NEGATIVE. ANIMAL MUTAGENICITY STUDIES WERE NEGATIVE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:BIOCONCENTRATION POTENTIAL IS LOW (BCF LESS THAN 100 OR LOG
KOW LESS THAN 3). LOG OCTANOL/WATER PARTITION COEFFICIENT (LOG KOW)
IS -1.36. HENRY'S LAW CONSTANT (H) IS 6.0E-08 ATM-M3/MOL.
BIOCONCENTRATI ON FACTOR (BCF) IS 10 IN GOLDEN ORFE.
BIODEGRADATION UNDER AEROBIC STATIC LABORATORY CONDITIONS IS HIGH
(BOD20 OR BOD28/THOD GREATER THAN 40%). 5-DAY BIOCHEMICAL OXYGEN
DEMAND (BODT) IS 0.78 P/P. 10- DAY BIOCHEMICAL OXYGEN DEMAND
(BOD10) IS 1.06 P/P.

Transport Information:US DOT NON-BULK: PROPER SHIPPING NAME- ETHYLENE
GLYCOL (FLEET CHARGE ANTIFREEZE). BULK: PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID NOS (ETHYLENE GLYCOL)
ID NUMBER: UN3082, HAZA RD CLASS 9, PACKING GROUP: PG III,
REPORTABLE QUANTITY: 5,000 LB. IATA: NON-BULK PROPER SHIPPING
NAME: ETHYLENE GLYCOL (FLEET CHARGE ANTIFREEZE) NOT REGULATED BY
IATA.

SARA Title III Information:SECTION 311/312- CATEGORIES: ACUTE HAZARD;
CHRONIC HAZARD. SECTION 312 - INVENTORY REPORTING: ETHYLENE GLYCOL
IS SUBJECT TO TIER I AND/OR TIER II ANNUAL INVENTORY REPORTING.
SECTION 313 - EMISSION R EPORTING: ETHYLENE GLYCOL IS SUBJECT TO
FORM R REPORTING REQUIREMENTS. SECTION 302 - EXTREMELY HAZARDOUS
SUBSTANCES: ETHYLENE GLYCOL IS NOT LISTED.
Federal Regulatory Information:TSCA INVENTORY: ETHYLENE GLYCOL LISTED
(CAS# 107-21-1). CLEAN AIR ACT (1990) - LIST OF HAZARDOUS AIR
CONTAMINANTS: LISTED. CERCLA: REPORABLE QUANTITY (RQ): 5,000
POUNDS (532 GALLONS).
State Regulatory Information:THIS PRODUCT CONTAINS THE FOLLOWING
CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: 1,4-
DIOXANE (CAS# 123-91-1), <=0.0086%; ACETALDEHYDE (CAS# 75-07-0),
<=0.1000 PPM. THIS PRODUCT CONT AINS THE FOLLOWING CHEMICAL(S)
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS AND/OR
OTHER REPRODUCTIVE HARM: ETHYLENE GLYCOL MONOMETHYL ETHER (CAS#
109-86-4), <=0.0009%.